Sweat evaporates from our bodies in order to cool us down, absorbing massive amounts of heat energy from its immediate surroundings. Its rate of evaporation is effected by several factors:
- If the temperature is increased, it evaporates faster.
- If humidity is reduced, it evaporates faster.
- If the pressure is reduced, the wind blows across it, or breathability is increased, it evaporates faster.
- If the sweat is spread out, its surface area increases for faster evaporation.
How the temperature varies from skin to exterior can be called the temperature gradient: it is usually significantly warmer on the inside and cooler on the outside.
It therefore makes sense to evaporate sweat directly off the skin as this is what requires cooling and is also at the warmest end of the temperature gradient. In fact, wicking sweat away from the skin (as many manufacturers advocate) would only make us cooler if it was being moved to a part of our clothing system with lower humidity or better breathability. In some thin clothing systems for sunny weather this is possible, but in windproof systems the humidity and breathability is typically constrained by the windproof (often waterproof/breathable) barrier, on the outside. This is why breathability and venting are so important.
When evaporation of sweat is slowed, cooling is degraded, you sweat more and the clothing system becomes damp. Wet clothing insulates less because conduction is increased, but this doesn't cool as effectively as evaporation, and continues to chill for some time after you stop. Sweating more also contributes to dehydration.
Some baselayers seek to spread or wick sweat across the skin for better cooling and faster drying, notably those made by Paramo, the GoLite C-Thru Lite and ProSkins. ProSkins fit like a second skin for especially effective cooling and drying. They don't feel too bad when they are wet because movement doesn't bring you into contact with a cold patch.
Thicker baselayers with brushed linings are often designed to wick moisture from the skin and keep you warm and dry (contrary to why you are sweating in the first place). This may be important if your shell doesn't breathe or ventilate well and can provide an absorbent buffer beneath your sack where evaporation is usually poor. On the other hand, thin baselayers that wick across the skin pull sweat to the sides of your sack and towards your vents, allowing it to evaporate away.
If you are serious about staying warm in the mountains make every effort to avoid sweating. Making steady progress, rather than short, fast bursts helps. Don't wear too much. Use the vents in your clothing and remove layers when they aren't needed - hats are usually easy to take off. Consider starting out cool, with minimal layers, but take an OverShell or Shelter to wear when you stop.